Chemometrics of Solvent Extraction of Mn(II) and Fe(III) Bis(salicylidene) Ethylenediamine Complexes in Acid Medium

Nworie Felix Sunday

doi:10.28991/HEF-2020-01-02-03

Authors

Nworie Felix Sunday
nworie.sunday@ebsu.edu.ng
Department of Industrial Chemistry, Ebonyi State University, Abakaliki,, Nigeria https://orcid.org/0000-0001-7909-7519

Vol. 1 No. 2 (2020): June

Research Articles

Downloads

PDF

Abstract
How to Cite
Metrics
References
License

In this study, the preparation and solvent extraction parameters of Mn(II) and Fe(III) -bis(salicylidene) ethylenediamine (H₂SAL) were modeled with classical statistical analyses processed using SPSS19.0 software. The linear correlation coefficients for Mn(II) were between 0.59 to 1.0, whereas for Fe(III), it was between 0.48-1.0. The F-values, a measure of the significance of the models, indicated that all the factors are needed, though to differing degrees, for the preparation and extraction of the metal complexes. The significance level for each model was lower than 5%, and as such, the relationship can be generalized to the whole process. The experiments indicated that the solvent extraction combined with the modelling method was accurate, efficient, and reproducible and could be applied on an industrial scale.

Doi: 10.28991/HEF-2020-01-02-03

Full Text: PDF

Sunday, N. F. (2020). Chemometrics of Solvent Extraction of Mn(II) and Fe(III) Bis(salicylidene) Ethylenediamine Complexes in Acid Medium. Journal of Human, Earth, and Future, 1(2), 71–77. https://doi.org/10.28991/HEF-2020-01-02-03

Download Citation

Lide, D. R. (2008). CRC Handbook of Chemistry and Physics. 88th Edition. CRC Press – Routledge, Oxfordshire, United Kingdom.

Rustamov, N. K., & Abbasova, G. G. (2014). Determination of Manganese in Tap Water by a New Extraction-Photometric Method. American Journal of Analytical Chemistry, 05(04), 275–280. doi:10.4236/ajac.2014.54034.

Ahmed, M. J., & Roy, U. K. (2009). A simple spectrophotometric method for the determination of iron (II) aqueous solutions. Turkish journal of chemistry, 33(5), 709-726.

Kostova, D. (2010). Determination of manganese by a new spectrophotometry method using toluidine blue. Journal of Analytical Chemistry, 65(2), 159–163. doi:10.1134/s1061934810020103.

Seleim, M. M., Abu-Bakr, M. S., Hashem, E. Y., & El-Zohry, A. M. (2009). Spectrophotometric determination of manganese (II) with Mordant Brown 33 in the presence of Tween 20 in some foods. Canadian Journal of Analytical Sciences and Spectroscopy, 54(2), 93-101.

Mghimi, M., Syed, A. A., Al-Okab, R. A., & Taghartapeh, M. R. (2010). Application of electrophilic coupling reaction as a novel spectrophotometric methods for the determination of manganese. In International Conference on Biology, Environment and Chemistry 1, 337-340.

Rauf, M. A., Ikram, M., & Ahmad, M. (2002). Spectrophotometric Studies of Ternary Complexes of Vanadyl, Manganese, and Iron Witho-Phenanthroline and Eosin. Journal of Trace and Microprobe Techniques, 20(2), 171–180. doi:10.1081/tma-120003722.

Arinze, J. C., Daniel, N. E., & Ogwuegbu, M. O. C. (2012). Synthesis and characterization of P-Nitrobenzoylpyrazolone-5 andits complexes of Manganese (II), Iron (III), Rhodium (III), Tungsten (VI) and Uranium (VI). Journal of Emerging Trends in Engineering and Applied Sciences, 3(1), 61-68.

El-Shahawi, M. S. (1991). Spectrophotometric Determination of Nickel(II)with Some Schiff Base Ligands. Analytical Sciences, 7(3), 443–446. doi:10.2116/analsci.7.443.

Kiran Kumar, T. N., & Revanasiddappa, H. D. (2003). Rapid and sensitive spectrophotometric determination of trace amounts of iron(III) using leuco Xylene cyanol FF. Analytical and Bioanalytical Chemistry, 376(7), 1126–1130. doi:10.1007/s00216-003-2023-x.

Brodowska, K., & Lodyga-Chruscinska, E. (2015). ChemInform Abstract: Schiff Bases - Interesting Range of Applications in Various Fields of Science. ChemInform, 46(11). doi:10.1002/chin.201511346.

Kandil, F., Al Zoubi, W., & Chebani, M. K. (2012). The Synthesis and Characterization of New Schiff Bases and Investigating them in Solvent Extraction of Chromium and Copper. Separation Science and Technology, 47(12), 1754–1761. doi:10.1080/01496395.2012.660554.

Ogwuegbu, M. O. C., & Chileshe, F. (2000). Coordination Chemistry in Mineral Processing. Mineral Processing and Extractive Metallurgy Review, 21(6), 497–525. doi:10.1080/08827500008914176.

Zhang, W., Loebach, J. L., Wilson, S. R., & Jacobsen, E. N. (1990). Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes. Journal of the American Chemical Society, 112(7), 2801–2803. doi:10.1021/ja00163a052.

Nworie, F. S., & Nwabue, F. I. (2014). Solvent extraction studies of metal complexes derived from a tetradentate schiff base Bis (salicylidene) ethylenediamine (H2SAL) in acid medium. International Journal of Innovative and Applied Research, 2(6), 66-75.

Cozzi, P. G. (2003). Enantioselective Alkynylation of Ketones Catalyzed by Zn(Salen) Complexes. Angewandte Chemie International Edition, 42(25), 2895–2898. doi:10.1002/anie.200351230.

Nworie, F. S., Nwabue, F. I., Oti, W. J. O., & Eluu, S. (2015). Bis (2-methylyidenephenol) diaminoethane (H2BMPDE) as analytical reagent for solvent extraction studies of Fe (II), Fe (III), Mn (II) and Cr (III). Journal of Chemical and Pharmaceutical Research, 7(11), 30-40.

Sunday, N. F., & Ikenna, N. F. (2017). Synthesis, optimization, characterization and antimicrobial studies of Cu (II) and Co (III) complexes of bis (2, 2-methylylidenephenol) diaminoethane. Chemistry Journal of Moldova, 12(2), 41-49.

Nwabue, F. I., & John, J. (2015). Extractive-Spectrophotometric Determination of Fe(II), Fe(III), Mn(II) and Cr(III) through complexation with 2, 2 I-ethylenebis (nitrilomethylidene) diphenol (H2EBNMDP). Research Journal of Chemical Sciences, 5(5): 99.

Nworie, F. S., Nwabue, F. I., Elom, N. I., & Eluu, S. O. (2016). Schiff bases and schiff base metal complexes: from syntheses to applications. Journal of Basic and Applied Research, 2(3), 295-305.

Nworie, F. S., & Nwabue, F. I. (2014). Chemometrics of liquid-liquid extraction of metal chelates 1. Nature and Science, 12, 87-96.

Acceptance Rate:	29%
Review Speed:	63 days
Issue Per Year:	4
Number of Volumes:	5
Number of Issues:	20
Number of Articles:	154
Number of Reviewers:	327
Number of Contributors:	540
Contributing Countries:	57
No. of Scopus Citations:	785
No. of WoS Citations:	694
No. of Google Citations:	1394
Google h-index:	22
Google i10-index:	51
Abstract Views:	138,409
PDF Download:	127,181

Chemometrics of Solvent Extraction of Mn(II) and Fe(III) Bis(salicylidene) Ethylenediamine Complexes in Acid Medium

Authors

Downloads

Login

submission

Publisher & Affiliated Societies

Indexing & Abstracting

SidebarMenu

IndexedBy

Indexed In

twitter

Social Media

Analytics

Analytics

Information

Most Cited Articles

Alternative Fuel: Hydrogen and its Thermodynamic Behaviour

Utilization Management to Ensure Clean Water Sources in Coastal Areas

Eco-Friendly Asphalt Approach for the Development of Sustainable Roads

Assessment of the Presence of Pharmaceutical Compounds in Wastewaters and in Aquatic Environment

Address

Contact Info:

Chemometrics of Solvent Extraction of Mn(II) and Fe(III) Bis(salicylidene) Ethylenediamine Complexes in Acid Medium

Authors

Downloads

Login

submission

Publisher & Affiliated Societies

Indexing & Abstracting

SidebarMenu

social

Journal Imprint

Journal Metrics

IndexedBy

Indexed In

twitter

Social Media

Analytics

Analytics

Information

Most Cited Articles

Alternative Fuel: Hydrogen and its Thermodynamic Behaviour

Utilization Management to Ensure Clean Water Sources in Coastal Areas

Eco-Friendly Asphalt Approach for the Development of Sustainable Roads

Assessment of the Presence of Pharmaceutical Compounds in Wastewaters and in Aquatic Environment